Presentation on the topic nitrogen. Nitrogen and its properties, presentation for a chemistry lesson (grade 9) on the topic “suffocating air”


Application. Liquid nitrogen is used as a refrigerant and for cryotherapy. Industrial applications of nitrogen gas are due to its inert properties. Gaseous nitrogen is fire- and explosion-proof, prevents oxidation and rotting. In petrochemistry, nitrogen is used to purge tanks and pipelines, check the operation of pipelines under pressure, and increase the production of fields. In mining, nitrogen can be used to create an explosion-proof environment in mines and to expand rock layers. In electronics manufacturing, nitrogen is used to purge areas that do not allow the presence of oxidizing oxygen. In a process traditionally carried out using air, if oxidation or decay are negative factors, nitrogen can successfully replace air. An important area of ​​application of nitrogen is its use for the further synthesis of a wide variety of compounds containing nitrogen, such as ammonia, nitrogen fertilizers, explosives, dyes, etc. Large quantities of nitrogen are used in coke production (“dry quenching of coke”) during unloading coke from coke oven batteries, as well as for “pressing” fuel in rockets from tanks to pumps or engines. In the food industry, nitrogen is registered as a food additive E941, as a gaseous medium for packaging and storage, a refrigerant, and liquid nitrogen is used when bottling oils and non-carbonated drinks to create excess pressure and an inert environment in soft containers. Content.

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Nitrogen

“Nitrogen oxide” - 4. Give examples of reactions that prove the acidic properties of nitric oxide (III). Nitric oxide (V). Several nitrogen oxides are known. +1 +2 +3 +4 +5. NO. N2O. All nitrogen oxides, except N2O, are toxic substances. Nitrogen is capable of exhibiting several oxidation states from -3 to +5. +3 +5 2NO2 + H2O = HNO2 + HNO3.

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Repeat and consolidate knowledge about the structure of the atom and molecule of nitrogen. Study the physical and chemical properties of nitrogen. Reveal the role of nitrogen in nature.

“There is no life without nitrogen, for it is an indispensable component of proteins.” D.N. Pryanishnikov

K. Scheele and G. Cavendish obtained nitrogen in 1772. D. Rutherford described the preparation and properties in 1787. Lavoisier proposed the name nitrogen - “lifeless” (and - no, zoe - life). Numerous names: unclean gas, suffocating gas, spoiled air, flammable air, saltpeter, putrefactive agent, deadly gas, nitrogen, etc.

Natural form Earth's shell Salts of ammonium and nitric acid Lithosphere, hydrosphere Nitrogen Atmosphere Nitrogen and ammonia from volcanoes Lithosphere Compounds in some types of fuel (oil, coal) Lithosphere Nucleic acids, protein substances Biosphere

2nd period, 5th group, main subgroup Contains 5 electrons on the outer energy level +7)) 2 5 Oxidizing agent N 0 + 3e -  N -3 * Make up formulas for compounds of N with Li, Ca, Al. Reducing agent N 0 –1,2,3,4,5e -  N +1 ,N +2 ,N +3 ,N +4 ,N +5 * Make up the formulas of the oxides 3 1 2 4

N N N  N BOND: -COVALENT NON-POLAR -TRINARY -STRONG MOLECULE: -VERY STABLE -LOW REACTIVITY 1 3 4 2

Gas without color, odor and taste. Poorly soluble in water. Slightly lighter than air, density 1.2506 kg/m3 Tº pl.= -210 º C Tº boil.= -196 º C Does not support respiration and combustion

Oxidizing N 2 0 2N -3 When heated with other metals (Ca, Al, Fe) At room tº only with Li * At high tº, p, kat (Fe, Al, K oxides) with H 2 Reductive N 2 0 2N +2 * At tº electric arc (3000 - 4000 º C) with O 2

Application Production of ammonia and nitric acid. Creation of an inert atmosphere in metallurgy. Production of nitrogen fertilizers. Production of explosives. Liquid nitrogen in medicine. Saturation of steel surface to increase strength

Preparation In industry - from liquid air In the laboratory - by decomposition of unstable nitrogen compounds

1 m 2 o 3 l 4 e 5 k 6 u 7 l 8 a Securing new material

Reflection (work in pairs) Name of the topic - one noun Description of the topic - two adjectives Description of the action - two verbs + gerunds (or three verbs) Attitude to the topic - four words The essence of the topic - one word.

Paragraph No. 23, report sheet, exercise 5 work tetra Write a story on the topic: “The Journey of Nitrogen in Nature” Answer the questions: How can you prove experimentally that there is nitrogen in the air? To transport vegetables and fruits over long distances, refrigerators are used, in which liquid NITROGEN is used as a refrigerant. What properties is this based on?

Slide 2

A liquid nitrogen

Liquid nitrogen is non-explosive and non-toxic. Liquid of transparent color. It has a boiling point of −195.75 °C.

By evaporating, nitrogen cools the fire and displaces the oxygen necessary for combustion, so the fire stops. Since nitrogen, unlike water, foam or powder, simply evaporates and disappears, nitrogen fire extinguishing, along with carbon dioxide, is the most effective method of extinguishing fires from the point of view of preserving valuables.

Slide 3

Application of liquid nitrogen

  • for cooling various equipment and machinery;
  • for cooling computer components during extreme overclocking
  • Slide 4

    • Liquid nitrogen is used in cosmetology. for the treatment of vulgar, plantar and flat warts, papillomas, hypertrophic scars, vulgar acne, rosacea.
    • In the food industry, nitrogen is registered as a food additive E941, as a gaseous medium for packaging and storage, a refrigerant, and liquid nitrogen is used when bottling oils and non-carbonated drinks to create excess pressure and an inert environment in soft containers.
  • Slide 5

    Behavior of substances in liquid nitrogen

    Substances in liquid nitrogen become brittle

    Slide 6

    Liquid nitrogen burns

    You should cool the affected areas of the body with water or cold objects, administer painkillers, and apply bandages made from sterile dressings or improvised materials to the wounds.

    Slide 7

    Caisson disease

    Caisson sickness occurs when there is a rapid decrease in pressure (for example, when ascending from depth, leaving a caisson or pressure chamber, or ascending to a height). In this case, nitrogen gas, previously dissolved in the blood or tissues, forms gas bubbles in the blood vessels. Characteristic symptoms include pain or neurological impairment. Severe cases can be fatal.

    Slide 8

    Chemical properties of nitrogen

    • 6Li + N2 = 2Li3N
    • N2 + 3H2 = 2NH3
    • N2 + O2 = 2NO
  • Slide 9

    Chemically, nitrogen is a fairly inert gas due to its strong covalent bond, while atomic nitrogen is chemically very active. Of the metals, free nitrogen reacts under normal conditions only with lithium, forming nitride:

    • 6Li + N2 = 2Li3N

    As temperature increases, the activity of molecular nitrogen increases. When nitrogen reacts with hydrogen under heating, elevated pressure and the presence of a catalyst, ammonia is formed:

    • N2 + 3H2 = 2NH3

    Nitrogen combines with oxygen only in an electric arc to form nitrogen oxide (II):

    • N2 + O2 = 2NO
  • Slide 10

    Nitric acid

    The boiling point of nitric acid is +83 °C, the freezing point is –41 °C, i.e. under normal conditions it is a liquid. The pungent odor and the fact that it turns yellow during storage is explained by the fact that the concentrated acid is unstable and partially decomposes when exposed to light or heating.

    4HNO3 = 2H2O + 4NO2 + O2.

    Slide 11

    Interaction with metals

    Concentrated nitric acid

    • Me+ HNO3(conc.) → salt + water + NO2

    Noble metals (Au, Ru, Os, Rh, Ir, Pt) do not interact with concentrated nitric acid, and a number of metals (Al, Ti, Cr, Fe, Co, Ni) are passivated at low temperatures with concentrated nitric acid. The reaction is possible with increasing temperature

    • Ag + 2HNO3(conc.) → AgNO3 + H2O + NO2.
  • Slide 12

    Dilute nitric acid

    The reduction product of nitric acid in a dilute solution depends on the activity of the metal involved in the reaction:

    Active metal

    • 8Al + 30HNO3(dil.) → 8Al(NO3)3 + 9H2O + 3NH4NO3

    Medium activity metal

    • 10Cr + 36HNO3(dil.) → 10Cr(NO3)3 + 18H2O + 3N2

    Low-active metal

    • 3Ag + 4HNO3(dil.) → 3AgNO3 + 2H2O + NO
  • Slide 13

    Preparation of nitric acid

    • NaNO3 + H2SO4 = NaHSO4 + HNO3
    • 4NH3 + 5O2 → 4NO + 6H2O (Conditions: catalyst – Pt, t = 500˚С)
    • 2NO + O2 → 2NO2
    • 4NO2 + O2 + 2H2O ↔ 4HNO3
  • Slide 14

    Application of nitric acid

    • Production of nitrogen and complex fertilizers.
    • Production of explosives.
    • Production of dyes.
    • Medicine production.
    • Production of films, nitro-varnishes, nitro-enamels.
    • Production of artificial fibers.
    • As a component of a nitrating mixture for trawling metals in metallurgy.
  • Slide 15

    Ammonia

    Ammonia - NH3, hydrogen nitride, under normal conditions - a colorless gas with a sharp characteristic odor (the smell of ammonia).

    Ammonia is almost twice as light as air. The solubility of NH3 in water is extremely high - about 1200 volumes (at 0 °C) or 700 volumes (at 20 °C) in volume.

    Ammonia (in European languages ​​its name sounds like “ammoniac”) owes its name to the Ammon oasis in North Africa, located at the crossroads of caravan routes. In hot climates, urea (NH2)2CO, contained in animal waste products, decomposes especially quickly. One of the decomposition products is ammonia. According to other sources, ammonia got its name from the ancient Egyptian word amonian. This was the name given to people who worshiped the god Amon. During their rituals, they sniffed ammonia NH4Cl, which, when heated, evaporates ammonia.

    Slide 16

    Ammonia is dangerous

    In medicine, a 10% aqueous solution of ammonia is known as ammonia. The pungent odor of ammonia irritates specific receptors of the nasal mucosa and promotes excitation of the respiratory and vasomotor centers, therefore, in case of fainting or alcohol poisoning, the victim is allowed to inhale vapors of ammonia

    Ammonia is dangerous if inhaled. In acute poisoning, ammonia affects the eyes and respiratory tract, and at high concentrations it can be fatal. Causes severe coughing, suffocation, and with a high concentration of vapors - agitation, delirium. Upon contact with skin - burning pain, swelling, burn with blisters.

    First aid: rinse eyes and face with water, put on a gas mask or a cotton-gauze bandage moistened with a 5% solution of citric acid, rinse exposed skin with plenty of water, immediately leave the source of infection.

    If ammonia gets into the stomach, drink several glasses of warm water with the addition of one teaspoon of table vinegar per glass of water and induce vomiting.

    Reaction of ammonia with water and acids

    Both an aqueous solution of ammonia and ammonium salts contain a special ion - the ammonium cation NH4, which plays the role of a metal cation. It is obtained as a result of the fact that the nitrogen atom has a free (lone) electron pair, due to which another covalent bond is formed with the hydrogen cation, which is transferred to ammonia from acid or water molecules:

    This mechanism for the formation of a covalent bond, which arises not as a result of the sharing of unpaired electrons, but due to a free electron pair present in one of the atoms, is called donor-acceptor.

    • NH3 + HCl = NH4Cl
    • 2NH3 + H2SO4 = (NH4)2SO4↓
    • NH3 + H20<->NH4 + OH-

    If you add a few drops of phenolphthalein to an ammonia solution, it will turn crimson, i.e. it will show an alkaline environment:

  • Slide 20

    Ammonium salts

    enter into an exchange reaction with acids and salts:

    • (NH4)2SO4 + Ba(NO3)2 → BaSO4 ↓ + 2NH4NO3(NH4)2CO3 + 2HCl → 2NH4Cl + H2O + CO2

    react with alkali solutions to form ammonia - a qualitative reaction to ammonium ion:

    • NH4Cl + NaOH → NaCl + NH3 + H2O
    • decompose when heated NH4Cl → NH3 + HCl
    • NH4NO3 → N2O + 2H2O
    • (NH4)2Cr2O7 → N2 +Cr2O3+ 4H2O
  • View all slides

    Slide 1

    The letters are given: R, Z, I, O, A, P, T, M. These letters contain the name of an element about which it is known: - 78% of air consists of a simple substance formed by this chemical element; - the hydrogen compound of this element helps to bring a person out of fainting; - ancient manuscripts are stored in the atmosphere of this gas; - the acid formed by this element dissolves silver, but does not dissolve iron and aluminum; - this acid forms salts that are beneficial to plants, but harmful to people; - if the Russian names of chemical elements are arranged in alphabetical order, then the first one will be...

    Slide 2

    Nitrogen is the eternal source of tantalum torment of humanity, it is the eternal torment of hunger in the midst of an ocean of abundance. M. Kamen (American biochemist).

    Slide 3

    Slide 4

    According to the UN, one third of the world's population is hungry, and every minute several people die from this cause. What is the importance of nitrogen for the existence of life on Earth? Why is nitrogen associated with problems of food shortage and hunger? How can nitrogen solve this problem?

    Slide 5

    Sub-problems. History of the discovery of nitrogen. Prove the high reactivity of the element nitrogen. What physical properties are characteristic of the simple substance nitrogen? What reactions does molecular nitrogen enter into and what properties does it exhibit in them? What properties of nitrogen are its applications based on?

    Slide 6

    Give definitions of concepts. Atmosphere. Covalent chemical bond. Molecular crystal lattice. Oxidation-reduction reaction. Oxidizing agent, reducing agent.

    Slide 7

    Project assignments. When, by whom and how was the element nitrogen discovered? How common is the element in nature? What explains the discrepancy between its name and symbol? What is the importance of nitrogen for the existence of life on earth? Why is the literal translation “lifeless”? What do you know about the element nitrogen? Give its general characteristics. Write the electronic formula and electronic diagram of the structure of the nitrogen atom. Determine the characteristic oxidation states. Why is the chemical element nitrogen highly reactive?

    Slide 8

    Project assignments. What physical properties are characteristic of the simple substance nitrogen? Draw a diagram of the structure of a nitrogen molecule. What is the mechanism of formation and the nature of the chemical bond in the nitrogen molecule? Why is the nitrogen molecule inert? What reactions does molecular nitrogen enter into and what properties does it exhibit in them? Give examples of reactions that characterize the chemical properties of nitrogen. Why, despite the high nitrogen content in the air, does life on our planet not stop?

    Slide 9

    Project assignments. How is nitrogen obtained in industry? What properties of nitrogen are its applications based on? What is the essence of the cycle of the element nitrogen in nature? Why is nitrogen called the element of war in some cases, and the element of life and peace in others?

    Slide 10

    Nominations. "The most scientific." "The most ineresting". "The most original." "Most Illustrated"
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